Lithium Intercalation in Bilayer Graphene Devices(Springer Theses)

双层石墨烯器件的锂嵌入

物理学史

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1657.00
发货周期:外国库房发货,通常付款后3-5周到货
出  版 社
出版时间
2018年12月10日
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ISBN
9783030023652
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页      码
116
语      种
英文
版      次
2018
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图书简介
This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.
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