Classical Thermodynamics of Fluid Systems:Principles and Applications

图书简介

The aim of this book is to provide an in-depth view of the subject with all its mathematical complexity while keeping the focus practical. The book covers the subject in an innovative way, from the first principles of thermodynamics to applied topics of interest for practicing engineers and researchers. From the first chapters it takes out the myth of the mysterious nature of entropy and the remoteness of the Gibbs, Helmohltz and other functions, integrating them to the representation of physical phenomena. It provides a concise description of the fundamental concepts and uses real-world examples to show how to solve practical problems.

Part I: Fundamentals. Basic Concepts and Definitions. The First and Second Laws of Thermodynamics. The Concept of Entropy. Conservation of Energy in an Open Flow System. Definition of Enthalpy. The Algebra of State Functions. The Helmholtz and Gibbs Functions. Calculation of Changes in the Value of Thermodynamic Properties. Part II: Mixtures. Partial Molar Properties and Property Changes by Mixing. The Chemical Potential and the Gibbs-Helmholtz Equation. The Principles of Physical and Chemical Equilibrium. The Phase Rule and Duhem Theorem. Generality of the Thermodynamic Treatment. The Ideal Gas and Ideal Gas Mixtures. The Use of Fugacity and Activity in Equilibrium Studies. Calculation of Fugacities from Equations of State (EOS). Fugacity of a Mixture and of Its Components. Fugacities and Activities in Liquid Mixtures of Non Electrolytes. Activity Coefficients and Excess Properties. Mixture Behavior, Stability and Azeotropy. The Thermodynamics of Aqueous Electrolyte Solutions. Part III: Applications. The Thermodynamics of Chemical Reactions. The Thermodynamics of Equilibrium Based Separation Processes. Heat Effects in Pure Compounds and Mixtures. Adsorption of Gases in Solids. Part IV: Selected Topics. The Thermodynamics of Flow of Compressible Fluids. Elements of Statistical Thermodynamics. Statistical Thermodynamics Basis of Equations of State. Statistical Thermodynamics Basis of Excess Gibbs Functions. The Activity Coefficients of Individual Ions. Measurements and Modeling. Part V: Appendices. Appendix A. Material Balances in Open Flow Systems. Appendix B. Working with the Virial EOS. Appendix C. Working with the PRSV EOS. Appendix D. Working with ASOG-KT.

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Classical Thermodynamics of Fluid Systems:Principles and Applications 流体系统的经典热力学：原则和应用 化学史

Classical Thermodynamics of Fluid Systems:Principles and Applications

流体系统的经典热力学：原则和应用
化学史