图书简介
Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. This book covers fundamental research on using mesoporous MOFs for emerging applications of major industrial, environmental and academic importance, especially for purification and separations of water and liquid fossil fuels.
Contents Preface List of Illustrations Chapter 1 ? Introduction Chapter 2 - Post-synthetic Modifications of Mesoporous MOFs for Adsorption-based Applications 2.1 Post-synthetic Modifications of MIL-101 for Adsorption and Catalysis in Solution 2.2 Post-synthetic Modifications of MIL-100 for Adsorption and Catalysis in Solution 2.3 The PSM of Mesoporous MOFs other than MIL-101 and MIL-100 for Applications Based on Adsorption Chapter 3 - Mechanistic Studies of Activation of Mesoporous MOFs Chapter 4 - Stability of Mesoporous MOFs in Water 4.1 Water Stability of MIL-101(Cr) 4.2 Water Stability of Chemically Modified MIL-101(Cr) 4.3 Water Stability of MIL-101(Fe), MIL-101(Al) and MIL-101(V) 4.4 Water Stability of MIL-100(Fe) 4.5 Water Stability of MIL-100(Cr) 4.6 Water Stability of MIL-100(Al) 4.7 Water Stability of Chemically Modified MIL-100 4.8 Water Stability of Mesoporous MOFs other than MIL-101 and MIL-100 Chapter 5 - Adsorption of Organic Dyes by Mesoporous MOFs in Water 5.1 Adsorption of Cationic Dyes on MIL-101 5.2 Adsorption of Cationic Dyes on MIL-100 5.3 Adsorption of Anionic Dyes on MIL-101 5.4 Adsorption of Anionic Dyes on MIL-100 Chapter 6 - Adsorption of Biologically Active Compounds on Mesoporous MOFs in Water 6.1 Adsorption of Small Molecule Medicinal Drugs on MIL-101 6.2 Adsorption of Small Molecule Medicinal Drugs on MIL-100 6.3 Adsorption of Biologically Active Organic Compounds on MIL-100, MIL-101 and Similar MOFs 6.4 Adsorption of Large Molecule Biologically Active Compounds on Miscellaneous Mesoporous MOFs Chapter 7 - Adsorption of Miscellaneous Organic Compounds in Water Chapter 8 - Adsorption of Inorganic Ions on Mesoporous MOFs from Water Chapter 9 - Adsorption of Aromatic N-Heterocyclic Compounds from Liquid Fossil Fuels 9.1 Aromatic N-Heterocyclic Compounds in Fossil Fuels 9.2 Adsorptive Denitrogenation of Liquid Fossil Fuels 9.3 Adsorption of Aromatic N-Heterocyclic Compounds from Fossil Fuels on MIL-101 9.4 Adsorption of Aromatic N-Heterocyclic Compounds from Fossil Fuels on MIL-101 Chapter 10 - Adsorption of Aromatic Sulfur Compounds from Liquid Fuels 10.1 Aromatic Sulfur Compounds in Liquid Fossil Fuels 10.2 Methods of Desulfurization of Liquid Fossil Fuels 10.3 Adsorption of Aromatic Sulfur Compounds from Liquid Fossil Fuels on MIL-101 10.4 Adsorption of Aromatic Sulfur Compounds from Liquid Fossil Fuels on Modified MIL-101 10.5 Adsorption of Aromatic Sulfur Compounds from Liquid Fossil Fuels on MIL-101 10.6 Adsorption of Aromatic Sulfur Compounds from Liquid Fossil Fuels on Modified MIL-101 10.7 Adsorption of Aromatic Sulfur Compounds on Mesoporous MOFs other than MIL-100 and MIL-101 Chapter 11 - Adsorption of Miscellaneous Organic Compounds from Non-Aqueous Solutions 11.1 Adsorption of Organic Compounds on Mesoporous MOFs 11.2 Adsorption of Large-Molecule Biologically Active Organic Compounds on Mesoporous MOFs Chapter 12 - Encapsulation and Release of Medicinal Drugs by Mesoporous MOFs 12.1 Therapy with Engineered Nanoparticles 12.2 Mesoporous MOFs as Drug Carriers 12.3 Encapsulation and Controlled Desorption of Anti-Cancer Small Molecule Drugs 12.4 Encapsulation and Controlled Release of Anti-Viral Drugs 12.5 Encapsulation and Release of Miscellaneous Bio-Active Compounds Chapter 13 - Research on Mesoporous MOFs for Industrial Applications Summary List of Abbreviations Index
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