图书简介

Section 1: Laying the Foundations; Basics 1: Structures of Organic Compounds; Habit 1: Always Draw Structures with Realistic Geometry; Basics 2: Functional Groups and R Groups; Basics 3: Naming Organic Compounds; Practice 1: Drawing Structures from Chemical Names; Basics 4: Isomerism in Organic Chemistry - Constitutional Isomers; Practice 2: Constitutional Isomers and Chemical Names; Habit 2: Identifying When a Formula is Possible; Practice 3: Double Bond Equivalents; Common Error 1: Formulae, Functional Groups and Double Bond Equivalents; Habit 3: Ignore What Doesn’t Change; Basics 5: Electronegativity, Bond Polarisation and Inductive Effects; Practice 4: Bond Polarisation and Electronegativity; Basics 6: Bonding in Organic Compounds; Practice 5: Hybridisation; Basics 7: Bonding and Antibonding Orbitals; Basics 8: Introduction to Curly Arrows; Fundamental Reaction Type 1: Nucleophilic Substitution at Saturated Carbon; Practice 6: Electronegativity in Context; Fundamental Reaction Type 2: Elimination Reactions; Section 2: Building on the Foundations; Basics 9: Breaking Bonds - Linking Curly Arrows and Molecular Orbitals; Common Error 2: Curly Arrows; Basics 10: Conjugation and Resonance; Basics 11: Thermodynamic Definitions; Basics 12: Bond Dissociation Energy; Basics 13: Calculating Enthalpy of Reaction from Bond Dissociation Energies; Perspective 1: A Closer Look at Bond Dissociation Energies; Practice 7: Calculating Enthalpy of Reaction from Bond Dissociation Energy; Basics 14: Energetics and Reaction Profiles; Basics 15: How Fast Are Reactions?; Basics 16: Introduction to Carbocations, Carbanions and Free-Radicals; Basics 17: Carbocations 2 - More Factors Affecting Stability; Basics 18: Carbanions 2 - Stability and pKa; Perspective 2: A Scale for Carbocation Stability; Common Error 3: Methyl Groups are Electron-Releasing; Practice 8: Drawing Resonance Forms for Carbocations and Carbanions; Common Error 4: Resonance; Basics 19: The Hammond Postulate; Basics 20: Conjugation and Stability - The Evidence; Common Error 5: Carbocations and Carbanions; Basics 21: Reactivity of Conjugated Systems; Basics 22: Acid Catalysis in Organic Reactions Part 1; Reaction Detail 1: Nucleophilic Substitution at Saturated Carbon; Basics 23: What Defines a Transition State?; Perspective 3: Bonding Beyond Hybridisation; Fundamental Knowledge Recap 1: Bond Lengths and Strengths; Fundamental Knowledge Recap 2: pKa; Section 3: A Focus on Shape; Habit 4: Representing Stereochemistry - Flying Wedge and Newman Projections; Basics 23: Isomerism in Organic Chemistry - Configurational Isomers; Habit 5: Getting Used to Drawing Stereoisomers; Practice 9: Getting Used to Stereoisomers; Habit 6: Assignment of Stereochemistry - The Cahn-Ingold-Prelog Rules; Practice 10: Assigning Stereochemistry; Habit 7: Stereoisomers with Symmetry; Basics 25: Properties of Stereoisomers; Reaction Detail 2: Stereochemical Aspects of Substitution Reactions; Common Error 6: Substitution Reactions; Reaction Detail 3: Substitution with Retention of Configuration; Common Error 7: Stereochemical Errors; Section 4: Types of Selectivity; Basics 26: Selectivity in Organic Chemistry - Chemoselectivity; Basics 27: Selectivity in Organic Chemistry - Regioselectivity; Basics 28: Selectivity in Organic Chemistry - Stereoselectivity; Basics 29: Stereochemical Definitions Relating to Reactions; Section 5: Bonds Can Rotate; Basics 30: Isomerism in Organic Chemistry - Conformational Isomers; Practice 11: Conformational Analysis; Applications 1: Conformational Isomers 2; Applications 2: SN2 Substitution Reactions Forming Three-Membered Rings; Basics 31: Introduction to Cyclohexanes; Practice 12: Drawing Cyclohexanes; Applications 3: Substitution Reactions of Cyclohexanes; Basics 32: Quantifying Conformers of Cyclohexanes; Basics 33: More Conformers of Cyclohexanes and Related Compounds; Practice 13: Drawing More Complex Cyclohexanes; Common Error 8: Cyclohexanes; Section 6: Eliminating the Learning; Reaction Detail 4: Elimination Reactions; Perspective 4: A Continuum of Mechanisms; Basics 34: More Substituted Alkenes Are More Stable; Basics 35: Enthalpy Changes for Reactions Involving Anionic Species; Applications 4: Stereochemistry of Elimination Reactions; Basics 36: Stereospecificity; Applications 5: Elimination Reactions of Cyclohexanes; Common Error 9: Elimination Reaction; Reaction Detail 5: Allylic Substitution; Section 7: Building Skills; Worked Problem 1: Curly Arrows and Reaction Profiles; Worked Problem 2: Competing SN1 Substitution and E1 Elimination; Worked Problem 3: Competing SN2 Substitution and E2 Elimination; Worked Problem 4: Acid Catalysis in Organic Reactions Part 2; Worked Problem 5: Epoxide Opening Reactions; Worked Problem 6: Is cis-Cyclohexane-1,2-diol Really Achiral?; Worked Problem 7: The Furst-Plattner Rule; Worked Problem 8: SN2’ Stereochemistry and Conformations; Worked Problem 9: Complex Substitution Stereochemistry; Worked Problem 10: Cyclisation Reactions; Solution to Problem 1: Curly Arrows and Reaction Profiles; Solution to Problem 2: Competing SN1 Substitution and E1 Elimination; Solution to Problem 3: Competing SN2 Substitution and E2 Elimination; Solution to Problem 4: Acid Catalysis in Organic Reactions Part 2; Solution to Problem 5: Epoxide Opening Reactions; Solution to Problem 6: Is cis-Cyclohexane-1,2-diol Really Achiral?; Solution to Problem 7: The Furst-Plattner Rule; Solution to Problem 8: SN2’ Stereochemistry and Conformations; Solution to Problem 9: Complex Substitution Stereochemistry; Solution to Problem 10: Cyclisation Reactions

Trade Policy 买家须知